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Krapcho反应2019-04-17

β-酮酯,丙二酸酯,α-氰基酯或α-磺酰基酯在亲核试剂存在下脱羧的反应

反应机理

反应实例

参考文献

1. Krapcho, A. P.; Glynn, G. A.; Grenon, B. J. Tetrahedron Lett. 1967, 215 217. A. Paul Krapcho is a professor at the University of Vermont.

2. Duval, O.; Gomes, L. M. Tetrahedron 1989, 45, 4471-4476.

3. Flynn, D. L.; Becker, D. P.; Nosal, R.; Zabrowski, D. L. Tetrahedron Lett. 1992, 33, 7283-7286.

4. Martin, C. J.; Rawson, D. J.; Williams, J. M. J. Tetrahedron: Asymmetry 1998, 9, 3723-3730.

5. Gonzalez-Gomez, J. C.; Uriarte, E. Synlett 2002, 2095-2097.

6. Bridges, N. J.; Hines, C. C.; Smiglak, M.; Rogers, R. D. Chem. Eur. J. 2007, 13, 5207-5212.

7. Poon, P. S.; Banerjee, A. K.; Laya, M. S. J. Chem. Res. 2011, 35, 67-73. (Review).

8. Farran, D.; Bertrand, P. Synth. Commun. 2012, 42, 989-1001.

9. Adepu, R.; Rambabu, D.; Prasad, B.; Meda, C. L. T.; Kandale, A.; Rama Krishna, G.;Malla Reddy, C.; Chennuru, L. N. Org. Biomol. Chem. 2012, 10, 5554-5569.

10. Mason, J. D.; Murphree, S. S. Synlett 2013, 24, 1391–1394.

编译自:Name Reactions (A Collection of Detailed Reaction Mechanisms), Jie Jack Li, Krapcho reaction,page 356.

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