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Danheiser成环反应2020-02-09

α,β-不饱和酮和三甲基硅基丙二烯衍生物在路易斯酸催化下得到三甲基硅基环戊烯的反应。

反应机理




反应实例




参考文献

1. Danheiser, R. L.; Carini, D. J.; Basak, A. J. Am. Chem. Soc. 1981, 103, 1604. Rick L.

Danheiser earned his Ph.D. at Harvard under E. J. Corey. He is a professor at MIT.

2. Danheiser, R. L.; Carini, D. J.; Fink, D. M.; Basak, A. Tetrahedron 1983, 39, 935.

3. Danheiser, R. L.; Kwasigroch, C. A.; Tsai, Y.-M. J. Am. Chem. Soc. 1985, 107, 7233.

4. Danheiser, R. L.; Carini, D. J.; Kwasigroch, C. A. J. Org. Chem. 1986, 51, 3870.

5. Danheiser, R. L.; Tsai, Y.-M.; Fink, D. M. Org. Synth. 1988, 66, 1.

6. Danheiser, R. L.; Dixon, B. R.; Gleason, R. W. J. Org. Chem. 1992, 57, 6094.

7. Engler, T. A.; Agrios, K.; Reddy, J. P.; Iyengar, R. Tetrahedron Lett. 1996, 37, 327.

8. Friese, J. C.; Krause, S.; Schäfer, H. J. Tetrahedron Lett. 2002, 43, 2683.

编译自:Name Reactions (A Collection of Detailed Reaction Mechanisms), Jie Jack Li, Danheiser annulation,page  181-182.

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